منابع مشابه
Thermodynamics of polymer adsorption to a flexible membrane.
We analyze the structural behavior of a single polymer chain grafted to an attractive, flexible surface. Our model is composed of a coarse-grained bead-and-spring polymer and a tethered membrane. By means of extensive parallel tempering Monte Carlo simulations it is shown that the system exhibits a rich phase behavior ranging from highly ordered, compact to extended random coil structures, and ...
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We study the translocation of a flexible polymer through a pore in a membrane induced by its adsorption on trans side of the membrane. When temperature T is higher than Tc, the adsorption-desorption transition temperature, attractive interaction between polymer and membrane plays little role in affecting polymer conformation, leading to translocation time that scales as τ ∼ L3 where L is the po...
متن کاملMembrane curvature induced by polymer adsorption.
The phenomena resulting from interaction between polymers and membranes pose important problems for biological applications. Based on a scaling theory, we investigate the spontaneous curvature of a membrane induced by either flexible or semiflexible chain adsorption. Irrespective of chain stiffness, a weakly adsorbed polymer induces the membrane to bend away (to have a positive curvature) from ...
متن کاملIrreversibility and polymer adsorption.
Physisorption or chemisorption from dilute polymer solutions often entails irreversible polymer-surface bonding. We present a theory of the resultant nonequilibrium layers. While the density profile and loop distribution are the same as for equilibrium layers, the final layer comprises a tightly bound inner part plus an outer part whose chains make only fN surface contacts where N is chain leng...
متن کاملAdsorption of polydisperse polymer chains
The adsorption of polydisperse ideal polymer chains is shown to be sensitive to the large N tail of the distribution of chains. If and only if the number of chains decays more slowly than exponentially then there is an adsorption transition like that of monodisperse infinite chains. If the number decays exponentially the adsorption density diverges continuously at a temperature which is a funct...
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ژورنال
عنوان ژورنال: Polymer Journal
سال: 1976
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.8.150